NiFe-LDH/MXene nano-array hybrid architecture for exceptional capacitive lithium storage

. With the addition of MXene, the volume increases of the NiFe-LDH/MXene hybrid materials were also significantly alleviated. The thickness of the NiFe-LDH/MXene-500 electrode only increased by 31% after 50 cycles, which was far better than the prepared NiFe-LDH electrode. On the hand, the synergistic interaction of NiFe-LDH and MXene could stabilize the structure, reduce the activation barrier of ion/electron diffusion, and promote electron transfer in the electrode. MXene with high conductivity can be used as electrical and ionic conductance media to promote the transformation reaction of NiFe-LDH. According to the detailed kinetic analysis, the capacitance control behavior is the main electrochemical reaction of NiFe-LDH/MXene electrodes.