Enhancement of Piezoelectricity by Novel Poling Method of the Rare‐Earth Modified BiFeO3–BaTiO3 Lead‐Free Ceramics

Abstract In piezoceramics, the Curie temperature ( T C ) and piezoelectric coefficient ( d 33 ) are often inversely proportional, so it is very difficult to optimize high piezoelectricity and T C simultaneously. In addition, the high and temperature‐insensitive piezoelectric strain coefficient ( d 33 * ) with small hysteresis is also a longstanding obstacle in the development of lead‐free ceramics. In this work, a facile approach of donor doping strategy is adopted to replace Ba 2+ with Yb 3+ , Y 3+ , Sm 3+ , and Nd 3+ as a result, a high T C of 450 °C and outstanding d 33 of 422–436 pC N −1 is achieved by a novel magnetic poling method. Thermally‐stable and outstanding piezoelectric strain performance ( d 33 * ≈ 520–550 pm V −1 and Δ S T ≈ 10%) with small strain hysteresis ( H < 20%) results are highly encourageable in lead‐free ceramics. The main factors contributing to high piezoelectricity are the morphotropic phase boundary, suppression of defect charges by donor doping, thermal quenching, mesoscale nanodomain size, and novel poling method. The excellent piezoelectric performance and high T C of this work are superior to those of state‐of‐the‐art piezoceramics. The synergistic approaches of compositional design strategy and novel poling process in this work are highly beneficial for temperature‐insensitive piezoelectric sensor and actuator applications.