Donor–Acceptor Conjugated Microporous Polymer toward Enhanced Redox Kinetics in Lithium–Sulfur Batteries

Conjugated microporous polymers (CMPs) with porous structure and rich polar units are favorable for high-performance lithium-sulfur (Li-S) batteries. However, understanding the role of building blocks in polysulfide catalytic conversion is still limited. In this work, two triazine-based CMPs are constructed by electron-accepting triazine with electron-donating triphenylbenzene (CMP-B) or electron-accepting triphenyltriazine (CMP-T), which can grow on a conductive carbon nanotube (CNT) to serve as separator modifiers for Li-S batteries. CMP-B@CNT features faster ion transportation than the counterpart of CMP-T@CNT. More importantly, compared with acceptor-acceptor (A-A) CMP-T, donor-acceptor (D-A) CMP-B possesses a higher degree of conjugation and a narrower band gap, which are conducive to the electron transfer along the polymer skeleton, thus accelerating the sulfur redox kinetics. Consequently, the CMP-B@CNT functional separator endows Li-S cells with an outstanding initial capacity of 1371 mAh g^-1 at 0.1 C and favorable cycling stability with a capacity degradation rate of 0.048% per cycle at 1 C for 800 cycles. This work provides insight into the rational design of efficient catalysts for advanced Li-S batteries.