尖晶石
催化作用
锰
析氧
电子转移
电子结构
化学
化学物理
氧气
自旋(空气动力学)
对称性破坏
无机化学
光化学
材料科学
物理化学
计算化学
物理
冶金
有机化学
热力学
量子力学
电化学
电极
作者
Jiang-Hong Pan,Tinghui Li,Shan Yun
标识
DOI:10.1002/pssr.202300124
摘要
The spin‐related electronic occupation at the catalyst surface plays an important role in determining the acidic oxygen evolution reaction (OER), which can directly affect the bonding interaction and electron transfer with reactants. Herein, a series of manganese spinel oxides with good acidic stability are suggested to regulate the catalytic activity by surface engineering, in which the orbital splitting and electronic reconfiguration are strongly dependent on the surface symmetry breaking. The detailed analysis of electronic structure demonstrates that the magnetic moments of half‐filled 3 d metals at surface layers are obviously larger than that at the internal region. This difference in spin electron occupation makes it display a higher catalytic activity in acidic OER. This work suggests a new strategy to enhance catalytic activity by spin‐related surface engineering.
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