醋酸铅
材料科学
钙钛矿(结构)
铅酸蓄电池
阳极
阴极
电池(电)
醋酸
铅(地质)
化学工程
无机化学
二氧化铅
电极
有机化学
化学
物理化学
功率(物理)
工程类
地质学
物理
地貌学
量子力学
毒性
作者
Cong Liu,Zhinan Zhu,Yongmei Wang,Qiang Guo,Chenyun Wang,Peng Zhong,Zhan’ao Tan,Rusen Yang
出处
期刊:Nano Energy
[Elsevier]
日期:2020-03-01
卷期号:69: 104380-104380
被引量:29
标识
DOI:10.1016/j.nanoen.2019.104380
摘要
Lead-acid batteries contain significant amount of lead that is an important material for emerging perovskite solar cells. Here, we successfully recovered lead from lead-acid battery. Anode and cathode lead mud reacted with acetic acid (CH3COOH), and the produced high purity lead acetate (Pb(Ac)2) was tested with FTIR and XRD. The simple synthetic path is efficient and causes no secondary pollution. Furthermore, the recovered lead acetate was used to fabricate normal planar heterojunction perovskite solar cells (PerSCs) with a power conversation efficiency reaching 17.83%. In addition to lead acetate, CH3COOH was also found in the product of cathode mud. CH3COOH is beneficial for a compact and crystalline perovskite film and improves the device performance. Fabrication of perovskite solar cells with lead from spent batteries reduces the environmental impact of battery waste and promotes the development of new energy technology.
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