化学
芳基
苯乙烯
催化作用
赫克反应
还原消去
分子间力
氘
药物化学
氢化物
有机化学
分子
氢
烷基
共聚物
物理
量子力学
聚合物
作者
Liqun Jin,Jiaxia Qian,Nan Sun,Baoxiang Hu,Zhenlu Shen,Xinquan Hu
摘要
We developed a Pd-catalyzed intermolecular reductive Heck reaction to construct Csp2-Csp3 bonds between aryl bromides and olefins. Various styrene derivatives, acyclic and cyclic alkenes, were well tolerated to couple with varied aryl bromides in linear selectivity. Kinetic and deuterium labeling experiments suggested that i-PrOH provides a hydride through β-H elimination.
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