惰性
表面改性
化学
组合化学
惰性气体
激进的
高分子化学
药物化学
有机化学
物理化学
作者
Milan Pramanik,Rebecca L. Melen
出处
期刊:Chem
[Elsevier]
日期:2023-08-01
卷期号:9 (8): 2060-2062
被引量:1
标识
DOI:10.1016/j.chempr.2023.07.012
摘要
In this preview, we highlight Lin and co-workers’ recent findings published in Nature on the non-directed functionalization of chemically inert aliphatic C‒H bonds through the use of the hexamethyldisilazide anion (HMDS–, a reductant) and N-oxoammonium cation (TEMPO+, an oxidant) as a new class of frustrated radical pair. In this preview, we highlight Lin and co-workers’ recent findings published in Nature on the non-directed functionalization of chemically inert aliphatic C‒H bonds through the use of the hexamethyldisilazide anion (HMDS–, a reductant) and N-oxoammonium cation (TEMPO+, an oxidant) as a new class of frustrated radical pair.
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