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Preparation and properties of copper-aluminum composite strips and foils by horizontal continuous composite casting and rolling

材料科学 复合数 复合材料 条状物 图层(电子) 金属间化合物 铸造 脆性 变形(气象学) 电导率 无定形固体 冶金 合金 结晶学 化学 物理化学
作者
Jun Wang,Fan Zhao,Rui Wang,Xinhua Liu
出处
期刊:Journal of Materials Processing Technology [Elsevier BV]
卷期号:322: 118168-118168
标识
DOI:10.1016/j.jmatprotec.2023.118168
摘要

Cu-Al composite strips and foils show broad application prospects in electric power, new energy and other fields. However, they are difficult to prepare because of brittle interfacial intermetallic compounds and deformation ability difference between two matrix metals. In this study, Cu-Al composite strips and foils with the thickness of 350 μm and 50 μm are successfully prepared by horizontal continuous composite casting and rolling. Moreover, the effects of as-cast interfacial layer thickness on the properties of Cu-Al composite strips are studied. In the rolling, the as-cast interfacial layer is broken into fragments, so as to promote the Cu-Al matrix bonding at atomic scale. The local solid-state amorphous transformation is also observed at the newly formed Cu-Al interface. Therefore, with the as-cast interfacial layer thickness decreasing from 400 μm to 25 μm, the peeling strength of Cu-Al composite strips increasing from 15.1 N/mm to 17.5 N/mm. With the as-cast interfacial layer thickness decreasing from 400 μm to 65 μm, the conductivity of Cu-Al composite strips increases from 62.36%IACS to 72.58%IACS because the size of interfacial layer fragments is reduced. However, with the as-cast interfacial layer thickness decreasing from 65 μm to 25 μm, the conductivity decreases from 72.58%IACS to 68.65%IACS because the copper layer thickness after rolling is reduced. Large interfacial layer fragments hinder current conduction, but a suitable interfacial layer thickness can inhibit the coordinated deformation of Cu and Al, so as to increase the proportion of copper layer thickness in the entire composite strip.
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