化学
表面改性
富勒烯
铜
机械合成
偶联反应
光化学
球磨机
催化作用
有机化学
化学工程
物理化学
工程类
作者
H. X. Yang,Shiqi Ye,Gang Shao,Jun-Shen Chen,Guan‐Wu Wang
出处
期刊:Synlett
[Georg Thieme Verlag KG]
日期:2023-07-24
卷期号:34 (17): 2047-2051
摘要
Abstract An efficient mechanochemical copper-mediated coupling reaction of [60]fullerene with para- or meta-substituted N,N-dimethylanilines under solvent-free and ambient conditions has been developed. The present protocol provides N-methylfullerotetrahydroquinolines containing electron-withdrawing or electron-donating groups on the phenyl ring in a short reaction time and at room temperature. This reaction occurs through copper-mediated sp3 C–H functionalization of N,N-dimethylanilines under ball-milling conditions. In addition, a representative fullerotetrahydroquinoline has been applied in a perovskite solar cell device.
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