Perspective on Iron‐Based Phosphate Cathode for Commercial Sodium‐Ion Cells

Sodium (Na)-ion batteries (SIBs) have been considered as a potential device for large-scale energy storage. To date, some start-up companies have released their first-generation SIBs cathode materials. Among them, phosphate compounds, particularly iron (Fe)-based mixed phosphate compounds, present great potential for commercial SIBs owing to its low cost, environment friendly. In this perspective, a brief historical retrospect is first introduce to the development of Fe-based mixed phosphate cathodes in SIBs. Then, the recent development about this kind of cathode has been summarized. One of the iron-based phosphate materials, Na₃ Fe₂ (PO₄ )P₂ O₇ , is used as an example to roughly calculate the energy density and estimate the cost at the cell level to highlight their advantages. Finally, some strategies are put up to further increase the energy density of SIBs. This timely perspective aims to educate the community on the critical benefits of the Fe-based mixed phosphate cathode and provide an up-to-date overview of this emerging field.