Development of a Novel Zinc/Air Fuel Cell with a Zn Foam Anode, a PVA/KOH Membrane and a MnO2/SiOC-based Air Cathode

A new type of zinc/air fuel cell comprising a Hg/Pb free Zn foam anode, a PVA/KOH electrolyte membrane and a MnO2/SiOC-based cathode was developed in this work. The electrochemical activity of the zinc foam and air electrode was investigated in 6 M KOH under half-cell conditions. The pristine ZnO layer of the foam matrix favoured direct oxidation of the zinc particles to zinc oxide in 6 M KOH. In the laboratory cell, a specific energy of about 500 mWh g(-1) zinc was measured at 5 mA discharging current with a zinc foam, a PVA/KOH/H2O membrane and a MnO2+ Vulcan/carbon paper cathode. A correlation between cell performances and porosity of the zinc foam was found. However, stability of the Zn foam and SiOC GDL materials towards KOH should be improved.