期刊:RSC Advances [The Royal Society of Chemistry] 日期:2016-01-01卷期号:6 (3): 2019-2023被引量:50
标识
DOI:10.1039/c5ra22873e
摘要
We systematically studied the catalytic activity of the oxygen evolution reaction (OER) for the tetragonal spinel oxide Mn3−xCoxO4 (0 ≤ x < 1 and 1 < x ≤ 1.5). The OER catalytic activity of Mn3−xCoxO4 (0 ≤ x < 1) dramatically improved with an increase in Co content. We found that the OER activity of Mn3−xCoxO4 (0 ≤ x < 1) increased linearly with the suppression of the Jahn–Teller distortion. We therefore propose that the Jahn–Teller distortion plays an important role in the OER activities of compounds containing Mn3+. Mn3−xCoxO4 (0 ≤ x < 1) provides a rare case for directly studying the effect of the Jahn–Teller distortion on OER activity.