硅烯
硅
催化作用
纳米技术
化学
反应性(心理学)
反应中间体
表征(材料科学)
分子
过渡金属
组合化学
材料科学
有机化学
医学
病理
替代医学
作者
Shiori Fujimori,Shigeyoshi Inoue
出处
期刊:Elsevier eBooks
[Elsevier]
日期:2022-01-01
卷期号:: 1-51
标识
DOI:10.1016/b978-0-12-820206-7.00174-8
摘要
The chemistry of low-valent silicon compounds such as silylenes (R2Si:) and disilenes (R2SiSiR2) has evolved significantly over the past four decades and had long focused on the synthesis and characterization of hitherto unknown compounds. For the last decade, the low-valent silicon chemistry has been brought back into the spotlight as such species have potential applications in small molecule activation and catalysis. These highly reactive silicon compounds may offer environmentally friendly and cost-effective alternative to the current transition-metal mediated reactions. This chapter highlights the recent developments in silylene and disilene chemistry, including their reactivity towards small molecules such as H2, NH3, CO, CO2, alkenes, alkynes, and P4.
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