材料科学
分离器(采油)
涂层
聚丙烯
复合材料
聚烯烃
电解质
锂离子电池
纳米-
热失控
化学工程
纳米技术
图层(电子)
电池(电)
电极
功率(物理)
化学
物理化学
工程类
物理
热力学
量子力学
作者
Lei Ding,Ning Yan,Sihang Zhang,Ruizhang Xu,Tong Wu,Feng Yang,Ya Cao,Ming Xiang
标识
DOI:10.1021/acsami.1c22080
摘要
A shutdown-functionalized lithium-ion battery separator plays a pivotal role in preventing thermal runaway as cells experience electrical abuse, overcharge, and external short circuit. In this article, the trilayer separator endowed with shutdown function was fabricated by ingenious co-extrusion and bidirectional drawing based on the nano-Al2O3 coating online construction during the β-iPP cavitation process. The middle layer composed of nano-Al2O3, polyethylene, and polypropylene offers a shutdown temperature of 130 °C, and skin polypropylene layers with nano-Al2O3 coating hold optimized dimensional stability below the meltdown temperature. Crystal structure measurement and pore structure diagnosis disclose that nano-Al2O3 thins coarse fibrils and makes the porous structure uniform. De-bonding of nano-Al2O3/β-iPP interfaces retains nano-Al2O3 not only on the top surface of the separator but also on the pore intine to realize nano-Al2O3 coating online construction, consequently strengthening tensile capacity, dimensional stability to heating, and electrolyte affinity. Electrochemical tests further disclose that nano-Al2O3 coating stabilizes solid electrolyte interphase germination and heightens lithium-ion migration numbers, confining cell resistances and granting optimal high-rate performance and cycling ability. The proposed approach features simple technics, environment-friendly, continuous fabrication, and coating online construction, which can offer new ideas for the mass fabricating of the high-end separator.
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