Detection and Analysis of Corrosion and Contact Resistance Faults of TiN and CrN Coatings on 410 Stainless Steel as Bipolar Plates in PEM Fuel Cells

材料科学 腐蚀 介电谱 涂层 质子交换膜燃料电池 氮化铬 冶金 扫描电子显微镜 接触电阻 氮化钛 合金 复合材料 能量色散X射线光谱学 氮化物 电化学 化学工程 电极 图层(电子) 燃料电池 化学 物理化学 工程类
作者
Mohsen Forouzanmehr,Kazem Reza Kashyzadeh,Amirhossein Borjali,Anastas Ivanov,Mosayeb Jafarnode,Tat-Hean Gan,Bin Wang,Mahmoud Chizari
出处
期刊:Sensors [MDPI AG]
卷期号:22 (3): 750-750 被引量:16
标识
DOI:10.3390/s22030750
摘要

Bipolar Plates (BPPs) are the most crucial component of the Polymer Electrolyte Membrane (PEM) fuel cell system. To improve fuel cell stack performance and lifetime, corrosion resistance and Interfacial Contact Resistance (ICR) enhancement are two essential factors for metallic BPPs. One of the most effective methods to achieve this purpose is adding a thin solid film of conductive coating on the surfaces of these plates. In the present study, 410 Stainless Steel (SS) was selected as a metallic bipolar plate. The coating process was performed using titanium nitride and chromium nitride by the Cathodic Arc Evaporation (CAE) method. The main focus of this study was to select the best coating among CrN and TiN on the proposed alloy as a substrate of PEM fuel cells through the comparison technique with simultaneous consideration of corrosion resistance and ICR value. After verifying the TiN and CrN coating compound, the electrochemical assessment was conducted by the potentiodynamic polarization (PDP) and electrochemical impedance spectroscopy (EIS) tests. The results of PDP show that all coated samples have an increase in the polarization resistance (Rp) values (ranging from 410.2 to 690.6 Ω·cm2) compared to substrate 410 SS (230.1 Ω·cm2). Corrosion rate values for bare 410 SS, CrN, and TiN coatings were measured as 0.096, 0.032, and 0.060 mpy, respectively. Facilities for X-ray Diffraction (XRD), Scanning Electron Microscope (FE-SEM, TeScan-Mira III model and made in the Czech Republic), and Energy Dispersive X-ray Spectroscopy (EDXS) were utilized to perform phase, corrosion behavior, and microstructure analysis. Furthermore, ICR tests were performed on both coated and uncoated specimens. However, the ICR of the coated samples increased slightly compared to uncoated samples. Finally, according to corrosion performance results and ICR values, it can be concluded that the CrN layer is a suitable choice for deposition on 410 SS with the aim of being used in a BPP fuel cell system.
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