光致变色
化学
多金属氧酸盐
光催化
光化学
发光
氧化物
组合化学
催化作用
有机化学
材料科学
光电子学
作者
Jian‐Zhen Liao,Hailong Zhang,Sasa Wang,Jianping Yong,Xiao‐Yuan Wu,Rongmin Yu,Can‐Zhong Lu
出处
期刊:Inorganic Chemistry
[American Chemical Society]
日期:2015-04-10
卷期号:54 (9): 4345-4350
被引量:132
标识
DOI:10.1021/acs.inorgchem.5b00041
摘要
An effective strategy to synthesize multifunctional materials is the incorporation of functional organic moieties and metal oxide clusters via self-assembly. A rare multifunctional radical-doped zinc-based host-guest crystalline material was synthesized with a fast-responsive reversible ultraviolet visible light photochromism, photocontrolled tunable luminescence, and highly selective photocatalytic oxidation of benzylic alcohols as a result of blending of distinctively different functional components, naphthalenediimide tectons, and polyoxometalates (POMs). It is highly unique to link π-electron-deficient organic tectons and POMs by unusual POMs anion-π interactions, which are not only conducive to keeping the independence of each component but also effectively promoting the charge transfer or exchange among the components to realize the fast-responsive photochromism, photocontrolled tunable luminescence, and photocatalytic activity.
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