材料科学
催化作用
电极
电化学
掺杂剂
氢
燃料电池
退火(玻璃)
合金
化学工程
溅射
兴奋剂
冶金
纳米技术
化学
薄膜
光电子学
物理化学
工程类
生物化学
有机化学
作者
Xin Hao,Bin Yang,Ming Zhe Shen,Neng Huang
出处
期刊:Advanced Materials Research
日期:2012-12-01
卷期号:608-609: 880-883
标识
DOI:10.4028/www.scientific.net/amr.608-609.880
摘要
Seeking for reducing the cost of hydrogen energy fuel cells, one of the key points is reduce Pt loading in Pt/C catalytic electrode. Meanwhile, there is no negative impact about efficiency of electrode reactions. We manufactured PtCuCeO x catalyst for fuel cell by Ion Beam Sputtering (IBS). In this paper, the electrodes were processed by different annealing temperature and acid treatment temperature for post-processing. An appropriate amount of Cu dopant can reduce the Pt loading, and the catalytic performance won't reduce. Doping CeO x refined PtCu alloy crystal particle, active surface area of the electrode was improved. It had shown that Pt atoms accounted for 72%, Pt load 0.0618mg/cm2 by SEM + EDS and ICP-AES data. Performance of electrochemistry was increased by 40.5%. It showed the characteristics had low Pt loading with high performance of hydrogen evolution.
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