The depth profile of the pyroelectric coefficient effective values of a 0.72Pb(Mg 1/3 Nb 2/3 )O 3 -0.28PbTiO 3 ( PMN -0.28 PT ) single crystal is studied. It was shown that owing to high pyroelectric coefficients the secondary pyroelectric effect significally contributes (∼40%) to the total pyroelectric coefficient.