石墨烯
材料科学
聚苯胺
氧化物
五氧化二铁
织物
纳米复合材料
氨
氧化钒
纳米技术
化学工程
聚合
钒
聚合物
复合材料
化学
有机化学
冶金
工程类
作者
Xiaxia Xing,Lingling Du,Dongliang Feng,Chen Wang,Yingying Tian,Zhenxu Li,Huigang Liu,Dachi Yang
标识
DOI:10.1016/j.snb.2021.130944
摘要
Gaseous ammonia (NH3) under high concentration (e.g., larger than 25 ppm) is usually harmful to human organs. Instead, lower - concentration NH3 that is generated from human metabolism may serve as a biomarker for exhaled diagnosis of kidney disease. Ideally, wearable NH3 sensors integrated over cloths are highly desired for real-time monitoring. Here, twistable and tailorable nanocomposites (NCPs) textile has been developed for yielding wearable NH3 sensing, by which graphene oxide was firstly mixed with aniline monomer, and subsequently this mixture was in-situ polymerized by vanadium pentoxide to obtain a ternary NCPs of vanadium oxide, polyaniline and graphene oxide (V2O5/PANI/GO NCPs). Benefiting from the incorporation of PANI, V2O5 and GO, the V2O5/PANI/GO NCPs textile shows enhanced response (Rg/Ra −1 = 31.2 ± 1.8% @10 ppm NH3, room temperature), high stability that maintains 91.5% response after 56 days and excellent interfering selectivity. Remarkably, the V2O5/PANI/GO NCPs textile displays excellent twistability and tailorability. This strategy to V2O5/PANI/GO NCPs textile might be extended to nanosensing materials that could be integrated onto other textiles.
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