Influence of Solution Parameters on Phase Formation and Morphology of Electrospun Poly(vinylidene fluoride) Nanofiber

Poly(vinylidene fluoride), PVDF nanofibers were prepared using electrospinning method and the influence of electrospinning parameters such as PVDF concentration, DMF:Acetone ratio on the formation of different phases (α, \b{eta}, and γ) and desired morphology were investigated. A detail analysis of X-ray diffraction (XRD) and Fourier-transform infrared (FTIR) spectrometer data by deconvoluting the peaks were carried out for assigning and accurately identifying the peaks associated to a particular PVDF phase. SEM micrographs further helped in understanding the mechanism of desired \b{eta}-phase as well as in obtaining a condition for bead-free nanofibers. Interestingly, the mechanism of formation of phases are found mostly governed by the balance between surface tension and viscosity which is controlled by PVDF concentration and acetone content in the solution. A PVDF concentration of 20% (w/v) and DMF:Acetone ratio 1:1 was found suitable for maximum \b{eta}-phase in a completely bead-free nanofibers. The methodology and understanding of underlying mechanism of desired phase and morphology suggest a guideline for optimization of \b{eta}-phase and bead-free fibers in PVDF-based nanocomposite as well.