反应性(心理学)
催化作用
氧化物
硅
金属
纳米技术
材料科学
硼
可再生能源
过渡金属
块(置换群论)
主组元素
碳纤维
化学
冶金
有机化学
工程类
电气工程
几何学
替代医学
复合材料
复合数
医学
病理
数学
作者
Si Zhou,Wei Pei,Yanyan Zhao,Xiaowei Yang,Nanshu Liu,Jijun Zhao
标识
DOI:10.1038/s41524-021-00654-x
摘要
Abstract Activation of p -block elements to replace the rare and precious transition metals for renewable energy applications is highly desirable. In this review, we go over recent experimental and theoretical progress on the low-dimensional non-metal materials for clean energy production, including carbon, silicon, oxide, boron, and phosphorus-based nanostructures, with the p -block elements serving as active sites. We aim to elucidate the mechanism for triggering activity in different kinds of non-metal systems, and extract general principles for controlling the p -orbital-mediated reactivity from a theoretical point of view. The perspectives and challenges for developing high-efficiency non-metal catalysts are provided in the end.
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