荧光粉
色度
光子上转换
发光
分析化学(期刊)
材料科学
化学
光学
光电子学
物理
色谱法
作者
Hanchen Shen,Keqin Feng,Guangzhe Lu,Yoshio Sakka,Bin Lü
标识
DOI:10.1002/pssa.202100014
摘要
A series of (Lu 0.99− x Er 0.01 Yb x ) 2 O 3 and (Lu 0.99− x Er 0.01 Yb x ) 2 O 2 S ( x = 0—0.1) phosphor particles are prepared to investigate their upconversion luminescence properties. Under 980 nm pumping laser, the two phosphors both exhibit strong green emission at ≈520—573 nm and weak red emission at ≈648—688 nm arising from 4 S 3/2 / 2 H 11/2 → 4 I 15/2 and 4 F 9/2 → 4 I 15/2 transitions of Er 3+ , respectively. The optimum concentrations of Yb 3+ sensitizers are found to be 1.0 at% in oxide and 0.5 at% in oxysulfide, and their corresponding CIE chromaticity coordinates are (0.29, 0.69) and (0.33, 0.65). The Lu 2 O 2 S:Er/Yb phosphor exhibits ≈42 times higher luminescence intensity than the Lu 2 O 3 :Er/Yb contrast. More Yb 3+ addition further increases the proportion of red emission by the cross‐relaxation between adjacent Yb 3+ and Er 3+ and the multiphonon relaxation. The luminescence intensities of the two phosphors gradually increase as the laser output power increases and the upconversion mechanisms are both identified to be two‐phonon processes. The Lu 2 O 2 S:Er/Yb phosphor has a shorter lifetime than the Lu 2 O 3 :Er/Yb counterpart, whereas the lifetime for the red emission is longer than that for the green emission in each case.
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