Titania-Cellulose Hybrid Monolith for In-Flow Purification of Water under Solar Illumination

In this work, we report a versatile approach for the development of an in-flow purification water system under solar illumination. Cellulose nanofibrils (CNFs) were impregnated with TiO2 nanoparticles using water as a solvent to obtain hybrid CNF/TiO2 monoliths with 98% porosity. The opposite surface potential enables an electrostatically induced direct conjugation between TiO2 and CNFs. Scanning electron microscopy analysis of the surface morphology of the CNF/TiO2 monolith shows a homogeneous dense coating of titania nanoparticles onto the interconnected nanofibril network, providing a Brunauer-Emmett-Teller surface area of about 80 m2·g-1 for the hybrid monolith. Furthermore, compression tests reveal a good shape recovery after unloading, thanks to the highly flexible and mechanically stable three-dimensional structure. Finally, the CNF-based hybrids were tested as catalysts for the decomposition of organic pollutants under solar illumination. The tests were performed using a continuous flow reactor with a customized holder, allowing the solution to pass through the monolith. The results reveal a good photocatalytic activity and a long-term stability of the hybrid CNF/TiO2 monolith toward the decomposition of methyl orange and paracetamol. These features provide a proof of concept for the applicability of the hybrid CNF/TiO2 monoliths for in-flow purification of water under solar illumination, not only for model dyes but also for organic pollutants of high practical relevance.