材料科学
固化(化学)
多孔性
硅酸铝
氢氧化钙
水泥
扫描电子显微镜
结晶
粉煤灰
硅酸铝钙
底灰
水合物
复合材料
熔渣(焊接)
复合数
碱金属
氢氧化物
化学工程
化学
催化作用
有机化学
工程类
作者
Qi Sun,Xueda Wei,Tianlong Li,Lu Zhang
出处
期刊:Materials
[Multidisciplinary Digital Publishing Institute]
日期:2020-02-13
卷期号:13 (4): 855-855
被引量:21
摘要
A new type of cemented paste backfill (CPB) was prepared by using the bottom ash (BA) from a thermal power plant as an aggregate, alkali-activated slag as a binder, and an air-entraining agent as an admixture. Based on the central composite design (CCD) response surface method, the mix ratio was optimized, and scanning electron microscopy-energy dispersive spectroscopy (SEM-EDS) was performed on the optimal mix ratio. ImageJ software was utilized to determine the porosity of the experimental samples at various curing ages. The results indicate that the optimal mix ratio of the aggregate-binder ratio is 3.28, the alkali dosage is 3%, the solid content is 67.44%, and the air-entraining agent dosage is 0.1%. As the curing age increases, the porosity of CPB gradually decreases. A calcium aluminosilicate hydrate (C-A-S-H) gel is the main hydration product of alkali-activated slag. At the beginning of the hydration reaction, the slag gradually dissolves, and the C-A-S-H product binds the BA together. At 14 d, complete calcium hydroxide (CH) crystals appeared in the hydration product. Finally, the degree of C-A-S-H crystallization increased further to form a dense structure.
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