We report a facile and effective way to prepare graphene oxide/prussian blue/amino-terminated perylene derivative nanomaterials (GO/PB/PTCNH 2 ). The morphology, size and function of prepared carbon-based composite material were characterized by using field emission scanning electron microscope (FE-SEM), Fourier transform infrared (FTIR) spectroscopy, Raman spectroscopy, UV-vis spectrophotometer and electrochemical technology. As a result, PB nanoparticles and PTCNH 2 were uniformly dispersed on a typical origami GO sheet, and GO/PB/PTCNH 2 nanocomposite had good stability and electrochemical properties.