介孔材料
聚苯胺
材料科学
阴极
电池(电)
电化学
电导率
化学工程
锂硫电池
金属有机骨架
导电体
锂(药物)
吸附
纳米技术
聚合物
电极
化学
复合材料
催化作用
有机化学
物理化学
功率(物理)
内分泌学
工程类
物理
医学
量子力学
聚合
作者
Xiaofei Liu,Ya-Rui Wang,Hong Chen,Bo Li,Shuang‐Quan Zang
出处
期刊:Nano Research
[Springer Nature]
日期:2022-10-28
卷期号:16 (4): 4867-4873
被引量:8
标识
DOI:10.1007/s12274-022-5116-6
摘要
It was known that mesoporous metal-organic frameworks (MOFs) with hierarchical pores and unsaturated metal sites can effectively inhibit the shuttle effect of lithium polysulfides in lithium-sulfur battery, however, the unsatisfactory structural stability and electrical conductivity limit the application of mesoporous MOFs (MMOFs) in Li-S batteries. Aiming at sensible solutions, the conductive polyaniline (PANI) was incorporated into the MMOF to enhance the discharge capacity and the cycling stability of proposed Li-S batteries, as the stability and the conductivity of the MMOF cathode was improved simultaneously. The activated MMOF-PANI provides physical and chemical adsorption of polysulfides against their shuttle effect. Moreover, the introduction of PANI into the channels of MMOF effectively improves the conductivity of MMOF, thus improving the electrochemical performance of the MMOF-PANI-based batteries. Benefiting from these synergetic effects, the S@MMOF-PANI cathode delivers improved electrochemical performance including excellent rate performance and cycling stability. The battery shows an initial capacity of 777.7 mAh·g−1 at 2.0 C and a low decay rate of 0.06% per cycle in 1,000 cycles and approximately a repeatable rate performance.
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