Fabrication and Modification of Hydrotalcite‐Based Photocatalysts and Their Composites for CO2 Reduction: A Critical Review

Layered double hydroxides (LDHs), which resemble hydrotalcite, are a type of materials with cationic layers and exchangeable interlayer anions. They have drawn lots of curiosity as a high-temperature CO₂ adsorbent because of its quick desorption/sorption kinetics and renewability. Due to its extensive divalent or trivalent cationic metals, high anion exchange property, memory effect, adjustable behavior, bio-friendliness, easy to prepare and relatively low cost, the LDHs-based materials are becoming increasingly popular for photocatalytic CO₂ reduction reaction (CO₂RR). Fabrication and modification are good ways to move forward the advancement of LDHs-based catalysts, which will help chemistry and materials science make great progress. In this review we discussed structural characteristics and the methods for preparation and modification of LDHs-based photocatalysts. We also highlighted and discussed the major developments and applications in photocatalytic CO₂RR as well as the photocatalytic mechanism. The goal of the present review is to give a broad summary of the various LDHs-based photocatalysts and the corresponding design strategies, which could motivate more excellent research works to explore this kind of CO₂RR photocatalysts to further increase CO₂ conversion yield and selectivity.