流变学
干扰
粒状材料
材料科学
球体
软质材料
刚度(电磁)
机械
无定形固体
流量(数学)
本构方程
粘度
悬挂(拓扑)
流动特性
乳状液
弹性(物理)
经典力学
流变仪
复合材料
硬球
点(几何)
压实
作者
Wenjun Chen,Eric De Giuli,Matthieu Wyart,Yoël Forterre,Jasna Brujić,Bloen Metzger
标识
DOI:10.1073/pnas.2611013123
摘要
The flow of dense emulsions underlies applications from food and pharmaceutical processing to bioengineering, yet their rheology remains difficult to interpret under conventional volume-imposed conditions. Here, we change the control variable to osmotic-pressure using a recently developed instrument—the Capillarytron. This approach reveals a unified rheological structure where the osmotic pressure Π , by controlling droplet deformation, sets a pressure-dependent jamming volume fraction. When expressed in terms of the distance to this jamming point, all rheological data—spanning both Π - and ϕ -imposed measurements—collapse onto a single power-law divergence, akin to granular suspensions. The resulting constitutive relations provide a predictive, parameter-free description of emulsion rheology across Newtonian, yielding, and shear-thinning regimes. Together with recent results on soft spheres, our findings point to a unifying paradigm: Soft amorphous materials—from soft spheres to emulsions and likely foams—obey the same hard rules as granular suspensions, with softness entering through a pressure-dependent jamming point. This framework rationalizes Herschel–Bulkley rheology, assigns its parameters microscopic meaning, and opens perspectives on rigidity transitions in soft, deformable systems, including biological tissues.
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