Pulsed Sonoelectrochemical Synthesis of Size-Controlled Copper Nanoparticles Stabilized by Poly(N-vinylpyrrolidone)

A novel sonoelectrochemical method for the size-controlled synthesis of spherical copper nanoparticles in an aqueous phase was developed. In this study, poly(N-vinylpyrrolidone) (PVP) was used as the stabilizer for the copper clusters. The copper nanoparticles were characterized by XRD, UV-vis, IR, DLS, TEM, and HRTEM. The PVP was found to greatly promote the formation rate of copper particles and to significantly reduce the copper deposition rate, thereby making monodispersed copper nanoparticles. We could control the particle size by adjusting various parameters such as current density, deposition, temperature, and sonic power, and improve the homogeneity of the copper particles. The results also showed that the transfer rate of PVP-stabilized copper clusters from the cathodic vicinity to the bulk solution played an important role in the preparation of the monodispersed nanoparticles.