期刊:Organic Letters [American Chemical Society] 日期:2018-09-18卷期号:20 (19): 6104-6107被引量:18
标识
DOI:10.1021/acs.orglett.8b02528
摘要
The chemoselective oxidation of alcohols containing electron-rich sulfur functionalities (e.g., 1,3-dithianes and sulfides) into their corresponding carbonyl compounds with the sulfur groups can sometimes be a demanding task in modern organic chemistry. A reliable method for this transformation, which features azaadamantane-type nitroxyl radical/copper catalysis using ambient air as the terminal oxidant is reported. The superiority of the developed method was demonstrated by comparing it with various conventional alcohol oxidation methods.