Constructing ZnCo2O4@LDH Core–Shell hierarchical structure for high performance supercapacitor electrodes

Abstract In this article, ZnCo 2 O 4 nanowires deposited with two kinds of typical layered double hydroxides (Ni–Al,Co–Al LDH) are developed via scalable method. Two materials all display core–shell hierarchical structure. High specific capacitance of 2041 F g −1 and 1586 F g −1 are obtained for ZnCo 2 O 4 @Co–Al LDH and ZnCo 2 O 4 @Ni–Al LDH,respectively. Combining with active surface and synergistic effect, the role of hierarchical structure in enhancing performance is revealed. Moreover, two all solid state supercapacitors based on fabricated materials as positive electrodes, activated carbon as negative electrodes and PVA–KOH as polymer electrolyte are assembled. The maximum power and energy densities of ZnCo 2 O 4 @Co–Al LDH//AC are 6200 W kg −1 and 50.1 Wh kg −1 , respectively. While the power and energy densities of ZnCo 2 O 4 @Ni–Al LDH//AC are 3400 W kg −1 and 27.8 Wh kg −1 . At last, an energy storage–conversion system, based on solar cell as input device and assembled asymmetric supercapacitor ZnCo 2 O 4 @Co–Al LDH//AC as output device, is integrated as a self–sustaining power device, indicating its potential in practical applications.