Zero‐Dimensional Perovskite Nanocrystals for Efficient Luminescent Solar Concentrators

Abstract Luminescent solar concentrators (LSCs) are able to efficiently harvest solar energy through large‐area photovoltaic windows, where fluorophores are delicately embedded. Among various types of fluorophores, all‐inorganic perovskite nanocrystals (NCs) are emerging candidates as absorbers/emitters in LSCs due to their size/composition/dimensionality tunable optical properties and high photoluminescence quantum yield (PL QY). However, due to the large overlap between absorption and emission spectra, it is still challenging to fabricate high‐efficiency LSCs. Intriguingly, zero‐dimensional (0D) perovskites provide a number of features that meet the requirements for a potential LSC absorber, including i) small absorption/emission spectral overlap (Stokes shift up to 1.5 eV); ii) high PL QY (>95% for bulk crystal); iii) robust stability as a result of its large exciton binding energy; and iv) ease of synthesis. In this work, as a proof‐of‐concept experiment, Cs 4 PbBr 6 perovskite NCs are used to fabricate semi‐transparent large‐area LSCs. Cs 4 PbBr 6 perovskite film exhibits green emission with a high PL QY of ≈58% and a small absorption/emission spectral overlap. The optimized LSCs exhibit an external optical efficiency of as high as 2.4% and a power conversion efficiency of 1.8% (100 cm 2 ). These results indicate that 0D perovskite NCs are excellent candidates for high‐efficiency LSCs compared to 3D perovskite NCs.