激进的
黄药
化学
砜
二氧化硫
自由基取代
硫黄
自由基加成
自由基反应
有机化学
自由基引发剂
药物化学
聚合
聚合物
作者
Béatrice Quiclet‐Sire,Stéphanie Seguin,Samir Z. Zard
标识
DOI：10.1002/(sici)1521-3773(19981102)37:20<2864::aid-anie2864>3.0.co;2-w
摘要
A radical allylation reaction without tin: The xanthate group in aliphatic xanthates can be replaced by an allyl unit [Eq. (a)]. This radical chain reaction is propagated by ethyl radicals generated by extrusion of sulfur dioxide from ethanesulfonyl radicals, which are themselves derived from allyl ethyl sulfone.
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