半色移
化学
显色的
部分
腙
组合化学
色谱法
有机化学
量子力学
荧光
物理
作者
Karl J. Wallace,Jeroni Morey,Vincent M. Lynch,Eric V. Anslyn
摘要
Two simple chromogenic indicators (4) and (5), containing different supernucleophilic moieties, have been synthesized. Upon phosphorylation with two chemical warfare agent (CWA) simulants, a hypsochromic shift of approximately 50 nm is observed in an NaOH–DMSO solution. The oximate supernucleophile was found to be a better supernucleophile than the hydrazone moiety. Two X-ray crystal structures were obtained from unexpected synthetic side products obtained in this study. These will also be discussed.
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