MXene‐Enabled Pneumatic Multiscale Shape Morphing for Adaptive, Programmable and Multimodal Radar‐infrared Compatible Camouflage

Abstract Achieving radar‐infrared compatible camouflage with dynamic adaptability has been a long‐sought goal, but faces significant challenges owing to the limited dispersion relations of conventional material systems operating in different wavelength ranges. Here, this work proposes the concept of pneumatic multiscale shape morphing and design a periodically arranged pneumatic unit consisting of MXene‐based morphable conductors and intake platforms. During gas actuation, the morphable conductor transforms centimeter‐scale 2D flat sheets into 3D balloon shapes to enhance microwave absorption behavior, and also reconfigures micrometer‐scale MXene wrinkles into smooth planes in combination with cavity‐induced low heat transfer to minimize infrared (IR) signatures. Through theory‐guided reverse engineering, the final pneumatic matrix shows remarkable frequency tunability (2.64–18.0 GHz), moderate IR emissivity regulation (0.14 at 7–16.5 µm), rapid responsiveness (≈30 ms), wide‐angle operation (>45 ° ), and excellent environmental tolerance. Additionally, the multiplexed pneumatic matrix enables over 14 programmable coding sequences that independently alter thermal radiation without compromising radar stealth, and allows multimodal camouflage switching between three distinct compatible states. The approach may facilitate the evolution of camouflage techniques and electromagnetic functional materials toward multispectral, adaptability and intelligence.