Phosphine‐incorporated Metal‐Organic Framework for Palladium Catalyzed Heck Coupling Reaction

Abstract As an emerging material with the potential to combine the high efficiency of homogeneous catalysts and high stability and recyclability of heterogeneous catalysts, metal‐organic frameworks (MOFs) have been viewed as one of the candidates to produce catalysts of the next generation. Herein, we heterogenized the highly active mono(phosphine)‐Pd complex on surface of UiO‐66 MOF, as a catalyst for Suzuki and Heck cross coupling reactions. The successful immobilization of these Pd‐monophosphine complexes on MOF surface to form UiO‐66‐PPh 2 –Pd was characterized and confirmed via comprehensive set of analytical methods. UiO‐66‐PPh 2 –Pd showed high activity and selectivity for both Suzuki and Heck Cross Coupling Reactions. This strategy enabled facile access to mono(phosphine) complexes which are challenging to design and require multistep synthesis in homogeneous systems, paving the way for future MOF catalysts applications by similar systems.