Designing photonic microparticles with droplet microfluidics

Photonic materials with a periodic change of refractive index show unique optical properties through wavelength-selective diffraction and modulation of the optical density of state, which is promising for various optical applications. In particular, photonic structures have been produced in the format of microparticles using emulsion templates to achieve advanced properties and applications beyond those of a conventional film format. Photonic microparticles can be used as a building block to construct macroscopic photonic materials, and the individual microparticles can serve as miniaturized photonic devices. Droplet microfluidics enables the production of emulsion drops with a controlled size, composition, and configuration that serve as the optimal confining geometry for designing photonic microparticles. This feature article reviews the recent progress and current state of the art in the field of photonic microparticles, covering all aspects of microfluidic production methods, microparticle geometries, optical properties, and applications. Two distinct bottom-up approaches based on colloidal assembly and liquid crystals are, respectively, discussed and compared.