电解质
材料科学
阳极
电化学
化学工程
离子电导率
电池(电)
电化学窗口
复合数
锂(药物)
聚丙烯腈
枝晶(数学)
纳米纤维
静电纺丝
纳米技术
电极
聚合物
复合材料
化学
内分泌学
物理化学
工程类
功率(物理)
物理
医学
量子力学
数学
几何学
作者
Maoshuai Sun,Ji Li,Haocheng Yuan,Xiaoyue Zeng,Jinle Lan,Yunhua Yu,Xiaoping Yang
标识
DOI:10.1016/j.mtener.2022.101117
摘要
Lithium metal batteries with quasi-solid-state electrolytes are promising in the advanced energy storage system due to the high theoretical capacity and safety. Herein, a unique quasi-solid-state electrolyte (PUIE) containing 3D ion transport pathways based on UIO-66 has been constructed by a flexible process: electrospinning combined electrostatic spraying, followed by impregnation and roll press. In particular, UIO-66 with abundant Lewis acidic sites and channels enhances the ion transport and the restriction to anion in the electrolyte. The rationally designed PUIE-3 exhibits a high ionic conductivity of 1.08 mS/cm at 25 °C, a wide electrochemical window of 5.5 V, and a high Li+ transference number of 0.52. On the basis of the regulating effect of UIO-66, the growth of Li dendrites is significantly restrained and the electrolyte exhibits long-life electrochemical stability with Li anode during the Li plating/stripping. In consequence, lithium metal batteries loaded with PUIE-3 exhibit remarkable cycling and rate performance. Our results indicate that rational design polymer nanofiber/metal-organic framework membranes offer a new avenue for developing high performance quasi-solid-state electrolytes.
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