Singlet Oxygen-Dominated Peroxymonosulfate Activation by Layered Crednerite for Organic Pollutants Degradation in High Salinity Wastewater

Advanced oxidation processes (AOPs) have been widely studied for organic pollutants treatment in water, but the degradation performance of radical-dominated pathway was severely inhibited by the side reactions between the anions and radicals, especially in high salinity conditions. Here, a singlet oxygen (1O2)-dominated non-radical process was developed for organic pollutants degradation in high salinity wastewater, with layered crednerite (CuMnO2) as catalysts and peroxymonosulfate (PMS) as oxidant. Based on the experiments and density functional theory (DFT) calculations, 1O2 was the dominating reactive species and the constructed Cu-O-Mn with electron-deficient Mn captured electron from PMS promoting the generation of 1O2. The rapid degradation of bisphenol A (BPA) was achieved by CuMnO2/PMS system, which was 5-fold and 21-fold higher than that in Mn2O3/PMS system and Cu2O/PMS system. The CuMnO2/PMS system shown prominent BPA removal performance under high salinity conditions, prominent PMS utilization efficiency, outstanding total organic carbon (TOC) removal rate, wide range of applicable pH and good stability. This work unveiled that the 1O2-dominated non-radical process of CuMnO2/PMS system overcame the inhibitory effect of anions in high salinity conditions, which provided a promising technique to remove organic pollutants from high saline wastewater.