法拉第效率
阳极
材料科学
锂(药物)
钴
氧化钴
化学工程
铋
双金属片
氧化物
纳米技术
电极
冶金
化学
医学
工程类
物理化学
内分泌学
金属
作者
Winda Devina,Anith Dzhanxinah Mohd Sarofil,Christian Chandra,Hyeon Seo Park,Jae Ho Park,Kyung Yoon Chung,Wonyoung Chang,Jae-Hoon Kim
标识
DOI:10.1016/j.apsusc.2023.157013
摘要
Materials that undergo combined conversion and alloying reactions are promising as anodes for lithium storage application because they can accommodate multiple lithium ions. However, irreversible conversion reactions, large voltage hysteresis, poor rate capabilities, and low initial Coulombic efficiencies during continuous discharge–charge cycling make practical applications of conversion–alloying materials challenging. Herein, we present cobalt–bismuth oxide (CBO) nanoneedles, a new bimetallic material in which Li+-ion uptake proceeds stepwise, thus effectively suppressing volume expansion. During the initial lithiation stage, the CBO nanoneedles undergo a conversion reaction to form nanodomains of low-oxidation-state Coδ+ (δ ≤ 2) in a Li2O matrix. At the next potential platform, the Bi phase attracts Li+ ions via an alloying reaction, while the Coδ+/Li2O phase hinders excessive volume expansion. Consequently, the CBO electrode delivers a high reversible discharge capacity of 392 mAh g−1 at 50 mA g−1 for up to 100 cycles. Further, an ultrastable long-term capacity of 300 mAh g−1 at 250 mA g−1 is realized over 1000 cycles. The stepwise lithiation process decreases volume expansion significantly (by ∼10%), which leads to good cyclability. Owing to their ease of preparation and excellent performance characteristics, CBO nanoneedles are an attractive long-life anode material for lithium-ion batteries.
科研通智能强力驱动
Strongly Powered by AbleSci AI