Compatibility study of recycled Polypropylene (PP)/Poly(ethylene terephthalate) (PET) blends nanocomposites with PP‐g‐MAH: Modeling of twin screw extrusion

材料科学 聚丙烯 挤压 相容性(地球化学) 聚乙烯 复合材料 纳米复合材料 反应挤出 乙烯 高分子科学 有机化学 化学 催化作用
作者
Dajeong Gwon,Dohyeong Kim,Jaseung Koo
出处
期刊:Polymers for Advanced Technologies [Wiley]
卷期号:35 (9)
标识
DOI:10.1002/pat.6557
摘要

Abstract Although the utilization of recycled polymers is essential to sustain the environment, conventional recycled polymers face limitations in application due to the degradation of their properties caused by impurities. To solve the problem the performance deterioration of these recycled polymers, this study aimed to enhance their compatibility by chemically adding polypropylene‐graft‐maleic anhydride (PP‐ g ‐MAH) and physically manipulate a screw profile by using an extrusion simulation program. As a result of applying the optimized extrusion process set by the simulation program, significant improvements in the compatibility and dispersion of fillers within the polymer were observed through scanning electron microscopy image analysis. In addition, through detailed analysis of rheological data, the positive impact of adding compatibilizer and changing screw profile on rheological properties was demonstrated. As the compatibility of recycled polymer blends improved, tensile strength increased by approximately two‐fold and thermal conductivity was significantly improved, which were decisive factors in dramatically enhancing the performance of recycled polymers. These improved polymer properties provide an opportunity for recycled polymers to be applied more broadly and will expand the potential for new applications in various industrial fields.

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