化学
硫脲
对映选择合成
催化作用
组合化学
有机化学
转化(遗传学)
生物化学
基因
作者
Yousuke Yamaoka,Hideto Miyabe,Yoshiji Takemoto
摘要
A newly designed thiourea catalyst provides sufficient activation of organoboronic acids to facilitate the enantioselective Petasis transformation of quinolines even at low temperatures. A high degree of stereocontrol was achieved in the reaction of various quinolines and organoboronic acids by using a combination of H2O and NaHCO3 as additives.
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