倾点
蜡
复合数
肺表面活性物质
流变学
纳米复合材料
材料科学
化学工程
复合材料
原油
化学
吸附
粘度
流动特性
聚合物
制浆造纸工业
色谱法
填料(材料)
体积热力学
钠
浊点
作者
Fei Yang,An Feng,Guangyu Sun,Chuanxian Li,Bo Yao
出处
期刊:Energy & Fuels
[American Chemical Society]
日期:2025-12-08
卷期号:39 (50): 23556-23566
标识
DOI:10.1021/acs.energyfuels.5c04840
摘要
Nanocomposite pour point depressants (PPDs) represent a significant field of research within polymer PPDs, offering substantial enhancements in performance. This study investigates the impact of incorporating surfactant-modified Nano-Mg(OH) 2 into ethylene-vinyl acetate (EVA) PPD on the fluidity of Nanyang waxy crude oil. Rheological experiments revealed that the sole use of modified nanoparticles did not notably enhance flow properties. Findings indicate that the alkyl chain length of the surfactant influences the efficacy of the hybrid PPDs (C18 > C16 > C12), affecting the adsorption of EVA onto nanoparticles. Compared with EVA, the oil samples treated with NaSt-MDH/EVA had the best fluidity, with viscosity reduced by 58.85% and pour point further decreased by 4 °C. Sodium oleate, with its double-bond structure, hinders EVA adsorption, leading to a worse effect than EVA PPD. Through using normal and polarized light wax crystal micrographs, we elucidate the mechanism by which the composite PPD aggregates wax crystals, releasing a greater volume of liquid oil and thereby enhancing Nanyang crude oil’s fluidity. This paper presents the introduction of Nano-Mg(OH) 2 into nanocomposite PPDs for the first time, offering a novel approach to the development of new PPDs.
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