过电位
析氧
催化作用
分解水
电化学
材料科学
兴奋剂
杂原子
化学工程
氧气
水解
空位缺陷
无机化学
化学
电极
物理化学
结晶学
有机化学
光电子学
戒指(化学)
光催化
工程类
作者
Hang Zhang,Yushuai Jia,Yuan Li,Lei Wang,Chuying Ouyang,Shengliang Zhong
标识
DOI:10.1016/j.ijhydene.2022.10.124
摘要
The design and manufacture of strongly engaged, low-cost, and resilient oxygen evolution reaction (OER) electrocatalysts is the most challenging task in electrochemical hydrolysis. Herein, Ce and Ni co-doped MnO2 (NiCe/MnO2) nanosheets (NSs) with oxygen vacancy (VO) and abundant active sites have been prepared in one step employing a defect strategy. The co-doping of Ce/Ni on the one hand reduced the catalyst particle size and increased the specific surface area, which promoted the exposure of more active sites. On the other hand, heteroatom doping altered the species the crystalline surface, stimulating the formation of Vo and thus activating the catalyst performance simultaneously. The OER performance of NiCe/MnO2 NSs was significantly enhanced over the pure δ-MnO2, with an overpotential of 170 mV (10 mA cm−2), which was verified by density functional theory. This work shows a straightforward and practical method for making non-precious metal electrocatalysts with high electrochemical hydrolysis performance.
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