Catalyst-Controlled C–H Transformation of Pyrazolidinones with 1,3-Diynes for Highly Selective Synthesis of Functionalized Bisindoles and Indoles

An efficacious synthetic solution to offer functionalized bisindoles and indoles has been developed based on catalyst-controlled C–H functionalization of pyrazolidinones and 1,3-diynes with highly selective control of both chemoselectivity and regioselectivity. This straightforward pathway conquers chemo- and regioselectivity challenges concerning the use of 1,3-diynes.