光催化
纳米颗粒
燃烧
可见光谱
材料科学
化学工程
环境科学
废物管理
纳米技术
化学
光电子学
工程类
催化作用
有机化学
作者
Zhijie Zhang,Wenzhong Wang,Meng Shang,Wenzong Yin
标识
DOI:10.1016/j.jhazmat.2010.01.020
摘要
Visible-light-induced Bi(2)WO(6) photocatalyst has been successfully synthesized via a facile low-temperature combustion synthesis method, using glycine as the fuel. The photocatalytic activities of the as-synthesized samples were evaluated by the photodegradation of rhodamine B (RhB) and phenol under visible-light irradiation (lambda>420 nm). The results showed that the molar ratio of fuel to oxidizer had an important influence on the photocatalytic activities of the products. When the molar ratio of fuel to oxidizer was 1, the photocatalyst exhibited the highest degradation efficiency, which can completely degrade RhB with a concentration up to 10(-4)M within 75 min. Besides decoloring, the markable reduction of chemical oxygen demand (COD) was also observed in the degradation of RhB, further demonstrating the photocatalytic performance of Bi(2)WO(6). Additionally, the photocatalyst showed much enhanced visible photocatalytic efficiency, up to 94.2% in 4h, than the bulk Bi(2)WO(6) powder (SSR) in the degradation of phenol.
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