流变仪
固化(化学)
动力学
苯基异氰酸酯
聚氨酯
反应速率常数
材料科学
阿累尼乌斯方程
反应级数
动能
化学
高分子化学
化学工程
流变学
活化能
物理化学
复合材料
物理
工程类
量子力学
标识
DOI:10.1134/s2075113321010433
摘要
The kinetics of urethane formation during interaction of phenylisocyanate with hydroxyl-containing oligomers in the presence of shungite was researched using the method of IR spectroscopy. The constants of the reaction rate were determined by kinetic curves plotted in coordinates of a second order equation. The kinetics of curing of polyurethane compositions of “cold” curing, modified by shungite, was studied using the method of rotational rheometry and it was shown that the presence of the latter leads to acceleration of the curing process.
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