化学
分子
反应性(心理学)
组合化学
接受者
电子转移
选择性
光化学
电子受体
DNA
有机化学
催化作用
医学
物理
病理
生物化学
替代医学
凝聚态物理
作者
Yue Zhang,Shengdi Xia,Weihao Shi,Bizhen Lin,Xiao-Can Su,Weiwei Lu,Xinyuan Wu,Xuan Wang,Xiaojie Lu,Ming Yan,Xue-jing Zhang
出处
期刊:Organic Letters
[American Chemical Society]
日期:2022-10-24
卷期号:24 (43): 7961-7966
被引量:10
标识
DOI:10.1021/acs.orglett.2c03077
摘要
The photocatalyst-free electron donor-acceptor (EDA) complex photochemistry was deemed to expand the potential of photodriven radical chemistry. Here, we report a cross-coupling reaction of thianthrenium salt functionalized arenes and sodium sulfinates via a photopromoted single electron transfer (SET) process of an EDA complex. A series of biarylsulfones were obtained with high site-selectivity and reactivity. This mild and practical radical reaction could be applied on the bioactive and DNA-encoded molecules.
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