Carbon Dots‐Based Ultrastretchable and Conductive Hydrogels for High‐Performance Tactile Sensors and Self‐Powered Electronic Skin

Abstract Smart tactile sensing materials have excellent development prospects, including wearable health‐monitoring equipment and energy collection. Hydrogels have received extensive attention in tactile sensing owing to their transparency and high elasticity. In this study, highly crosslinked hydrogels are fabricated by chemically crosslinking polyacrylamide with lithium magnesium silicate and decorated with carbon quantum dots. Magnesium lithium silicate provides abundant covalent bonds and improves the mechanical properties of the hydrogels. The luminescent properties endowed by the carbon dots further broaden the application of hydrogels for realizing flexible electronics. The hydrogel‐based strain sensor exhibits excellent sensitivity (gauge factor 2.6), a broad strain response range (0–2000%), good cyclicity, and durability (1250). Strain sensors can be used to detect human motions. More importantly, the hydrogel can also be used as a flexible self‐supporting triboelectric electrode for effectively detecting pressure in the range of 1–25 N and delivering a short‐circuit current ( I SC ) of 2.6 µA, open‐circuit voltage ( V OC ) of 115 V, and short‐circuit transfer charge ( Q SC ) of 29 nC. The results reveal new possibilities for human–computer interactions and electronic robot skins.