水溶液
等离子体子
表面等离子共振
拉曼散射
拉曼光谱
分析物
萃取(化学)
原位
材料科学
纳米颗粒
膜
分析化学(期刊)
化学
纳米技术
色谱法
光电子学
光学
有机化学
生物化学
物理
作者
Chonghui Li,Baoyuan Man,Chao Zhang,Jing Yu,Guofeng Li,Meng Tian,Zhen Li,Xiaofei Zhao,Zhenxing Wang,Wanling Cui,Zhihui Wang,Jihua Wang,Xin Lin,Shicai Xu
标识
DOI:10.1016/j.snb.2023.134767
摘要
In situ surface-enhanced Raman scattering (SERS) detection of trace analytes with high sensitivity, especially in complex aqueous solution environments such as polluted water and biological fluids, remains an urgent task. Herein, a micro-extraction SERS membrane was developed by folding a plasmonic structure composing Au@Ag nanoparticles (NPs) and CuO nanospikes (NSs) via capillary action. In the numerical simulation using COMSOL software, we demonstrated that this structure with a parallel facing state can effectively trap and utilize incident photons to excite multiple plasmon resonance couplings. Moreover, it detected the molecular aqueous solution via capillary action in only 5 min. Benefitting from the dense volumetric hotspots and the simple trace extraction solution method, we utilized the proposed membrane for ultrasensitive in situ SERS detections of microcystin–LR (5 ×10–6 μg/L) toxins in drinking water, adenosine biological fluid (10–10 M), and carcinogenic malachite green (10–11 M) in seafood using a portable Raman instrument. The findings of this study provide promising insights for achieving in situ SERS detection of trace analytes in complex aqueous environments.
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